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Invention Publication
CN102690188A 几种天然氨基酸过渡金属配合物催化氧化四氢呋喃 无效 - 撤回

  • Patent Title: 几种天然氨基酸过渡金属配合物催化氧化四氢呋喃
  • Patent Title (English): Catalytic oxidation of tetrahydrofuran by several natural amino acid transition metal complexes
  • Application No.: CN201110067076.2
    Application Date: 2011-03-21
  • Publication No.: CN102690188A
    Publication Date: 2012-09-26
  • Inventor: 王吉德 , 吴雄 , 岳凡 , 张新村 , 王猛
  • Applicant: 新疆大学
  • Applicant Address: 新疆维吾尔自治区乌鲁木齐市胜利路14号
  • Assignee: 新疆大学
  • Current Assignee: 新疆大学
  • Current Assignee Address: 新疆维吾尔自治区乌鲁木齐市胜利路14号
  • Main IPC: C07C55/10
  • IPC: C07C55/10 ;  C07C51/23 ;  C07D307/33
几种天然氨基酸过渡金属配合物催化氧化四氢呋喃
Abstract:
本发明以天然氨基酸过渡金属配合物为催化剂，催化四氢呋喃在有氧条件下氧化为γ-丁内酯和丁二酸。方法包括下述步骤：先将天然氨基酸与过渡金属盐混合制备成催化剂，再将催化剂加入四氢呋喃中，在室温和加热条件下，用空气氧或纯氧气将四氢呋喃氧化成为丁二酸。
Abstract(English):

According to the invention, natural amino acid transition metal complexes are used as catalysts to catalyze tetrahydrofuran and tetrahydrofuran is oxidized under aerobic condition to gamma-butanolide and succinic acid. The method comprises the following steps of: mixing natural amino acid with transition metal salt to prepare the catalysts, adding the catalysts into tetrahydrofuran, and oxidizing tetrahydrofuran to succinic acid at room temperature and under heating condition by the use of atmosphere oxygen or pure oxygen.

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