A surface anticorrosion wear-resistant composite coating for a cylinder sleeve of an automobile engine applying bio-oil is disclosed. The coating comprises a Ni-Cu-Ce-La-P-Graphene composite material, and can be prepared by adopting a gradient chemical plating coating process. The coating is characterized in that: Ni, Cu, Ce, La and P in a special ratio, and Graphene are simultaneously deposited on the surface of the cylinder sleeve, and the composite coating with good anticorrosion and wear-resistant functions is prepared. The coating is advantageous in that: the binding force of the coating and a substrate is strong, compactness of the coating is high, the coating has excellent anticorrosion and wear-resistant effects especially for the bio-oil, a preparing method of the coating is simple, convenient, and prone to industrial production, and the coating can be widely used in the fields of metal material protection, mechanical surface treatment, energy-saving and environmental friendly automobiles, and the like.