The invention discloses a metal organic framework hybrid membrane as well as a preparation method and application thereof. The preparation method comprises the following steps: replacing inorganic parking with metal organic framework granules UiO-66 and/or UiO-66-NH2, preparing a casting membrane liquid from the metal organic framework granules together with high-molecular polymers, forming a membrane on the surface of a carrier by adopting a dipping-pulling method, and drying the membrane. The metal organic framework hybrid membrane disclosed by the invention has good application prospects in the field of separation of CO2 from flue gases and natural gases, and the hybrid membrane is simple in preparation process, low in cost and friendly to the environment, and has practical industrial application significance.