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CN107043370A 一种含吡咯‑2‑亚甲醛结构的席夫碱铁配合物吸波材料及制备方法 有权 许可

  • Patent Title: 一种含吡咯‑2‑亚甲醛结构的席夫碱铁配合物吸波材料及制备方法
  • Patent Title (English): Schiff base iron complex wave absorbing material containing pyrrole-2-aldehyde structure
  • Application No.: CN201710289445.X
    Application Date: 2017-04-27
  • Publication No.: CN107043370A
    Publication Date: 2017-08-15
  • Inventor: 刘峥 , 王浩 , 韩佳星 , 郭亚晋
  • Applicant: 桂林理工大学
  • Applicant Address: 广西壮族自治区桂林市七星区建干路12号
  • Assignee: 桂林理工大学
  • Current Assignee: 桂林理工大学
  • Current Assignee Address: 广西壮族自治区桂林市七星区建干路12号
  • Main IPC: C07D403/14
  • IPC: C07D403/14 ;  C09K3/00
一种含吡咯‑2‑亚甲醛结构的席夫碱铁配合物吸波材料及制备方法
Abstract:
本发明公开了一种含吡咯‑2‑亚甲醛结构的席夫碱铁盐吸波材料制备方法，制备共分为两步，第一步以吡咯‑2‑亚甲醛与1,3,5‑三嗪‑2,4,6‑三胺为原料，在无水乙醇中，以乙酸为催化剂，加热回流一定时间，可制备得到N,N'(吡咯‑2‑亚甲醛)缩1,3,5‑三嗪‑2,4,6‑三胺席夫碱化合物；第二步N,N'(吡咯‑2‑亚甲醛)缩1,3,5‑三嗪‑2,4,6‑三胺席夫碱和三氯化铁为原料，在无水乙醇中，加热回流一定时间，可制备得到N,N'(吡咯‑2‑亚甲醛)缩1,3,5‑三嗪‑2,4,6‑三胺席夫碱铁盐。上述席夫碱及其铁盐均具有良好的吸波性能。
Abstract(English):

The invention discloses a preparation method of a Schiff base iron salt wave absorbing material containing a pyrrole-2-aldehyde structure. The method comprises the following steps: 1, heating and refluxing pyrrole-2-aldehyde and 1,3,5-triazine-2,4,6-triamine which are used as raw materials in anhydrous ethanol for a certain time by adopting acetic acid as a catalyst in order to prepare an N,N'-(pyrrole-2-aldehyde)-1,3,5-triazine-2,4,6-triamine Schiff base compound; and 2, heating and refluxing the N,N'-(pyrrole-2-aldehyde)-1,3,5-triazine-2,4,6-triamine Schiff base and ferric trichloride which are used as raw materials in anhydrous ethanol for a certain time to prepare the N,N'-(pyrrole-2-aldehyde)-1,3,5-triazine-2,4,6-triamine Schiff base iron salt. The Schiff base and its iron salt have good wave absorbing property.

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