The present disclosure is drawn to ink fixative solutions, which can consist essentially of a polyvalent metal salt, a holdout additive, and water. The polyvalent metal salt can be present in an amount from about 1 wt % to about 5 wt %, with respect to the entire weight of the ink fixative solution. The holdout additive can be present in an amount from about 2 wt % to about 20 wt %, with respect to the entire weight of the ink fixative solution. The holdout additive can be polyethylene glycol, glycerol, carboxy methyl cellulose, hydroxy ethyl cellulose, a fatty acid, a fatty acid ethoxylate, or combinations thereof.