The invention relates to reverse extraction equipment and a method for TFA organic phases loading molybdenum. The equipment comprises a reverse extraction section and a washing section, wherein the reverse extraction section comprises a first-stage first-section mixing chamber, a first-stage two-section mixing chamber, ... , a first-stage n1-section mixing chamber, section partition plates, a mixed phase outlet, a reverse extraction clarification chamber, a reverse extraction liquid outlet, an ultra-stable interface control device I, a pre-mixing chamber, a reflux adjusting chamber, a reflux adjusting device, a reflux pipe, a water phase channel I and a stirring paddle. The method comprises the following steps that firstly, the load organic phases are pumped into the first-stage first-section mixing chamber; secondly, the mixed phases enter the reverse extraction clarification chamber through the mixed phase outlet, and clarification and phase splitting are carried out in the reverse extraction clarification chamber; and thirdly, the organic phases in the reverse extraction clarification chamber enter a first-stage washing mixing chamber through an organic phase channel I. According to the equipment and the method, the concentration of the molybdenum in a reverse extraction liquid can be improved to be about 180 g/L from 100 g/L, and the loss of the lean organic phase due to inclusion by a reverse extraction agent is reduced from 30% to 1% or below.