Invention Publication
EP0147666A2 Method of converting a precursor ceramic solid into a solid ceramic hydronium conductor
失效
一种用于陶瓷固体前体转化为固体陶瓷Hydroniumleiter过程。
- Patent Title: Method of converting a precursor ceramic solid into a solid ceramic hydronium conductor
- Patent Title (中): 一种用于陶瓷固体前体转化为固体陶瓷Hydroniumleiter过程。
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Application No.: EP84114556.8Application Date: 1984-11-30
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Publication No.: EP0147666A2Publication Date: 1985-07-10
- Inventor: Nicholson, Patrick Stephen , Yamashita, Kimihiro , Bell, Michael Francis , Sayer, Michael
- Applicant: Canadian Patents and Development Limited
- Applicant Address: 275 Slater Street Ottawa Ontario, K1A OR3 CA
- Assignee: Canadian Patents and Development Limited
- Current Assignee: Canadian Patents and Development Limited
- Current Assignee Address: 275 Slater Street Ottawa Ontario, K1A OR3 CA
- Agency: Patentanwälte Schulze Horn und Hoffmeister
- Priority: CA443793 19831220
- Main IPC: C01F7/04
- IPC: C01F7/04 ; C04B35/10
Abstract:
A method of converting a feed solid polycrystalline of alumina into a hydronium conductor requires the preselection of an appropriate feed ceramic preferably with a chemical forumula;
and with a t(S) of 0.37 ± 0.03 wherein
The crystallographic lattice is altered by placing the solid feed ceramic in an ionic solution or melt containing two or more ionic species of different ionic radii; the composition of the melt or solution being written: M,, M 2 (M 3 ...) X where M, and M 2 (and M 3 etc.) are ions of dissimilar size and as examples sodium, potassium, lithium and hydronium ions. After a time the material is removed, washed and subjected to a field effect exchange whereby the desired hydronium conducting solid ceramic having the following chemical composition is achieved;
where (a) (b) (c) = 0→I and a + b + c = I and Z is a stabilizer of the β" phase.
and with a t(S) of 0.37 ± 0.03 wherein
The crystallographic lattice is altered by placing the solid feed ceramic in an ionic solution or melt containing two or more ionic species of different ionic radii; the composition of the melt or solution being written: M,, M 2 (M 3 ...) X where M, and M 2 (and M 3 etc.) are ions of dissimilar size and as examples sodium, potassium, lithium and hydronium ions. After a time the material is removed, washed and subjected to a field effect exchange whereby the desired hydronium conducting solid ceramic having the following chemical composition is achieved;
where (a) (b) (c) = 0→I and a + b + c = I and Z is a stabilizer of the β" phase.
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