Methods for making low remnant free formaldehyde microcapsules and microcapsules made by same
Abstract:
Methods for producing microcapsules begin by preparing an emulsion of a surfactant, core material, and water, followed by the addition of a crosslinking agent and a melamine formaldehyde prepolymer, which is subsequently polymerized. The crosslinking agent is added before the melamine formaldehyde prepolymer, with a first addition or a second addition of a melamine formaldehyde prepolymer, or is divided for addition with both a first addition and a second addition of melamine formaldehyde prepolymer. The crosslinking agent is a mixture of a reaction product of a cyclic urea (U) and a multifunctional aldehyde (A), and at least one crosslinker selected from the following group: a reaction products of (i) an aminotriazine and at least one aldehyde selected from the group consisting of aliphatic monoaldehydes and multifunctional aliphatic aldehydes, (ii) urea and/or cyclic ureas and formaldehyde, or (iii) phenols and aliphatic monoaldehydes, or from alkoxycarbonylaminotriazines, or multifunctional isocyanates, epoxides, aziridines, and carbodiimides.
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