A method for collecting a compound from a surface, the method comprising providing a silicone adhesive collector comprising a silicone adhesive layer on a backing; contacting the silicone adhesives collector and a first solvent to provide a wetted collector; contacting the silicone adhesive layer of the silicone adhesive collector and a surface to be analyzed to provide a loaded collector; and removing the loaded collector from the surface to collect the compound. The disclosure also relates to a system for collecting a chemical compound from surfaces, the system comprising a silicone adhesive collector comprising a backing, and a silicone adhesive layer disposed on the backing; a first solvent; and instructions to dispose the first solvent on the silicone adhesive collector, the surface, or a combination thereof.