Invention Grant
- Patent Title: Polymer polyol quality
-
Application No.: US15263491Application Date: 2016-09-13
-
Publication No.: US10040903B2Publication Date: 2018-08-07
- Inventor: Rick L. Adkins , William E. Wood , Edward P. Browne
- Applicant: Covestro LLC , Covestro Deutschland AG
- Applicant Address: US PA Pittsburgh DE Leverkusen
- Assignee: COVESTRO LLC,COVESTRO DEUTSCHLAND AG
- Current Assignee: COVESTRO LLC,COVESTRO DEUTSCHLAND AG
- Current Assignee Address: US PA Pittsburgh DE Leverkusen
- Agent N. Denise Brown
- Main IPC: C08F283/06
- IPC: C08F283/06 ; C08F290/06 ; C08G65/333 ; B01J19/18 ; B01J19/24 ; C08F2/00 ; C08G18/63 ; C08F2/38 ; C08F283/00

Abstract:
This invention relates to a process for preparing a stable low viscosity polymer polyol having a solids content of at least about 30% by weight. This process comprise free-radically polymerizing one or more base polyols, one or more pre-formed stabilizers, and one or more ethylenically unsaturated monomers in the presence of one or more free-radical polymerization initiators, and one or more polymer control agents; in which the process is restarted after being stopped by (I) restarting the feed of base polyol and the initiator; (II) continuing the base polyol and initiator feed until the total feed amounts to at least 5% of the total reactor volume; and (III) restarting the feed of the ethylenically unsaturated monomers in which the ratio of monomers to total feed is ramped up to its final value over a period of not less than 25% of the reactor residence time. This process is particularly suitable for restarting the process of production after any planned or unplanned reactor shutdown.
Public/Granted literature
- US20180072846A1 POLYMER POLYOL QUALITY Public/Granted day:2018-03-15
Information query