A system for reducing carbon dioxide emissions from a flue gas generated via combusting a fossil fuel is provided. The system includes a calcination chamber and a sealing-purger. The calcination chamber is configured to receive a plurality of loaded sorbent particles and a plurality of heat-transferring particles such that the loaded sorbent particles are heated within the calcination chamber so as to release carbon dioxide. The sealing-purger includes at least one gravity driven moving particle bed. The at least one gravity driven moving particle bed allows the plurality of heat-transferring particles or the plurality of sorbent particles to enter or leave the calcination chamber while restricting the flue gas from entering the calcination chamber and the released carbon dioxide particles from leaving the calcination chamber.