Invention Grant
- Patent Title: Supported membrane functionalized with hexa- and octacyanometallates, process for the preparation thereof and separation process using same
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Application No.: US14430737Application Date: 2013-09-26
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Publication No.: US10068676B2Publication Date: 2018-09-04
- Inventor: Agnes Grandjean , Yves Barre , Eric Louradour , Didier Dhaler , Yannick Guari , Joulia Larionova
- Applicant: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES , CERAMIQUES TECHNIQUES ET INDUSTRIELLES (CTI) , CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE , UNIVERSITE DE MONTPELLIER 2
- Applicant Address: FR Paris FR Salindres FR Paris FR Montpellier
- Assignee: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES,CERAMIQUES TECHNIQUES ET INDUSTRIELLES (CTI),CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE,UNIVERSITE DE MONTPELLIER
- Current Assignee: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES,CERAMIQUES TECHNIQUES ET INDUSTRIELLES (CTI),CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE,UNIVERSITE DE MONTPELLIER
- Current Assignee Address: FR Paris FR Salindres FR Paris FR Montpellier
- Agency: Pearne & Gordon LLP
- Priority: FR1259228 20120928
- International Application: PCT/EP2013/070056 WO 20130926
- International Announcement: WO2014/049048 WO 20140403
- Main IPC: B01D24/00
- IPC: B01D24/00 ; B01D39/00 ; B01D39/14 ; B01D61/00 ; C02F1/44 ; G21F9/12 ; B01D67/00 ; B01D69/10 ; B01D71/02 ; C02F1/42 ; B01D37/02 ; C03C15/00 ; C03C17/00 ; C09K3/00 ; B01D69/14 ; C02F101/00

Abstract:
A supported membrane is provided comprising an inorganic, solid porous filtration membrane supported by an inorganic, solid porous support, said supported membrane comprising nanoparticles of a metal coordination polymer with CN ligands comprising Mn+ cations, where M is a transition metal and n is 2 or 3; and Alk+y[M′(CN)m]x− anions where Alk is an alkaline metal, y is 0, 1 or 2, M′ is a transition metal, x is 3 or 4, and m is 6 or 8; said Mn+ cations of the coordination polymer being bound through an organometallic or coordination bond to an organic group of an organic graft chemically attached to the surface of the filtration membrane, inside the pores of the filtration membrane, and optionally inside the pores of the support. The supported membrane may be used in a process for separating at least one metal cation and solid particles from a liquid medium containing the same.
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