An electrostatic wall sticker, use thereof, process for manufacturing the same, and method for storing and transporting the same are disclosed. The electrostatic wall sticker comprises the sticker body comprising a using layer made of plastic film which comprises a first side and a second side, and an adhesive layer made of plastic film which comprises a first side and a second side. It can effectively replace traditional wall stickers. This invention has the advantages of securely mounting on any dry surface without the need of adhesive agents, leaving no mark upon removal and being highly environmentally friendly. Also, this electrostatic wall sticker possesses the properties of face-to-face and rolling storage of static electricity, which makes transportation convenient.