Invention Grant
- Patent Title: Method for producing monoethylene glycol
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Application No.: US15747809Application Date: 2016-07-26
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Publication No.: US10077223B2Publication Date: 2018-09-18
- Inventor: Alexander Duefert , Rolf Pinkos , Michael Reiser , Philipp Brüggemann , Gerhard Theis
- Applicant: BASF SE
- Applicant Address: DE
- Assignee: BASF SE
- Current Assignee: BASF SE
- Current Assignee Address: DE
- Agency: Drinker Biddle & Reath LLP
- Priority: EP15178919 20150729
- International Application: PCT/EP2016/067706 WO 20160726
- International Announcement: WO2017/017074 WO 20170202
- Main IPC: C07C27/04
- IPC: C07C27/04 ; C07C29/149 ; B01J23/84 ; B01J23/843 ; B01J23/888 ; C07C67/08 ; B01J23/72 ; B01J21/02 ; C07C31/20 ; C07C29/90

Abstract:
Process for preparing monoethylene glycol (MEG) by metal-catalyzed reaction of a dialkyl oxalate of the formula I where R1 and R2 are each, independently of one another, methyl, ethyl, n-propyl or isopropyl, with hydrogen (H2), wherein the dialkyl oxalate (I) is used as melt or as a solution in a solvent, dialkyl oxalate (I) and H2 are used in a molar ratio of H2:dialkyl oxalate (I) in the range from 4.0 to 30 and the reaction is carried out continuously in a reactor at a cross-sectional loading of ≥10 m/s, a temperature in the range from 150 to 270° C., a pressure in the range from 150 to 390 bar and in the presence of a chromium-free heterogeneous catalyst comprising copper.
Public/Granted literature
- US20180222830A1 METHOD FOR PRODUCING MONOETHYLENE GLYCOL Public/Granted day:2018-08-09
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