A measurement method for a liquid crystal azimuthal angle of a liquid crystal panel and a measurement device are disclosed. The liquid crystal panel includes an upper polarization film, a lower polarization film disposed oppositely and liquid crystal molecules disposed there between. The method includes: when absorption axes of the upper and the lower polarization films are disposed as 0 degree and 90 degrees with respect to a horizontal direction, and are perpendicular to each other, measuring a first transmittance; when absorption axes of the upper and the lower polarization films are disposed as 45 degrees and 135 degrees with respect to the horizontal direction, and are perpendicular to each other, measuring a second transmittance; calculating to obtain the liquid crystal azimuthal angle of the liquid crystal panel according to the first transmittance and second transmittance. The present invention can measure the liquid crystal azimuthal angle quickly, simply, and effectively.