Invention Grant
- Patent Title: Aqueous polymer dispersion for paper with a copolymer of vinyl acetate and an acrylate monomer prepared in the presence of a starch derivative
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Application No.: US15303337Application Date: 2015-04-07
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Publication No.: US10167407B2Publication Date: 2019-01-01
- Inventor: Nico Veling , Lucia Jimenez Garcia , Dirk Lawrenz
- Applicant: BASF SE
- Applicant Address: DE Ludwigshafen
- Assignee: BASF SE
- Current Assignee: BASF SE
- Current Assignee Address: DE Ludwigshafen
- Agency: Oblon, McClelland, Maier & Neuistadt, L.L.P.
- Priority: EP14164346 20140411
- International Application: PCT/EP2015/057456 WO 20150407
- International Announcement: WO2015/155159 WO 20151015
- Main IPC: C09D131/04
- IPC: C09D131/04 ; C08F228/02 ; C08L3/04 ; C08F218/08 ; C08L31/04 ; C09D5/00 ; D21H19/54 ; D21H19/56 ; D21H21/18

Abstract:
The invention relates to a process for preparing an aqueous dispersion of a polymer P, which comprises the emulsion polymerization of vinyl acetate, an acrylate monomer, which is a C1-C10 alkyl acrylate or a C1-C10 methacrylate, an α,β-ethlyenically unsaturated C3-C8 carboxylic acid and at least one out of glycidyl methacrylate, glycidyl acrylate, allyl methacrylate and allyl acrylate, in the presence of a starch derivative. Optionally, an additional monomer is an ethylenically unsaturated sulfonic acid, an ethylenically unsaturated other monomer or both of them. Furthermore, the aqueous polymer dispersion obtainable from this process and a powder form thereof are disclosed. They are useful for a paper coating slip containing one of the aforementioned forms. A paper or a cardboard, which is coated with the paper coating slip, shows surface strength, which is expressed by a good dry pick resistance, a good wet pick resistance or good offset test results. The aqueous polymer dispersion or the powder form thereof is furthermore useful as a binder.
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