Systems and methods for document and product authentication are provided using a combination of interacting absorption and emission materials that are formed into covert optically encoded markings. The markings are formed from at least one emitter and at least one absorber, that exhibit a first emission in response to a first excitation of the emitter and a change in that emission in response to excitation of the absorber such that various combinations of emitter and absorber materials create a machine readable response that cannot be detected by the human eye.