Invention Grant
- Patent Title: Removal of hydrogen sulfide and sulfur recovery from a gas stream by catalytic direct oxidation and claus reaction
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Application No.: US15539257Application Date: 2015-12-23
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Publication No.: US10195565B2Publication Date: 2019-02-05
- Inventor: Michael Heisel , Benoit Mares
- Applicant: PROSERNAT
- Applicant Address: FR Puteaux
- Assignee: PROSERNAT
- Current Assignee: PROSERNAT
- Current Assignee Address: FR Puteaux
- Agency: Millen, White, Zelano and Branigan, P.C.
- Priority: EP14307188 20141224
- International Application: PCT/EP2015/081129 WO 20151223
- International Announcement: WO2016/102652 WO 20160630
- Main IPC: C10L3/10
- IPC: C10L3/10 ; C01B17/04 ; B01D53/52 ; B01D53/86 ; B01D53/90

Abstract:
A process for the removal of hydrogen sulfide and sulfur recovery from a H2S-containing gas stream by catalytic direct oxidation and Claus reaction through two or more serially connected catalytic reactors, wherein a specific control of the oxygen supplement is operated. The control and improvement of the process is obtained by complementing, in each major step of the process, the H2S-containing gas stream by a suitable flow of oxygen, namely before the H2S-containing gas stream enters the Claus furnace, in the first reactor of the process and in the last reactor of the process. Especially in application in a SubDewPoint sulfur recovery process the H2S/SO2 ratio is kept constant also during switch-over of the reactors R1 and R by adding the last auxiliary oxygen containing gas directly upstream the last reactor R so that the H2S/SO2 ratio can follow the signal of the ADA within a few seconds.
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