Invention Grant
- Patent Title: Method for the epoxidation of an olefin with hydrogen peroxide
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Application No.: US15550872Application Date: 2016-02-03
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Publication No.: US10196370B2Publication Date: 2019-02-05
- Inventor: Jürgen Stock , Joao André , Sebastian Imm , Matthias Pascaly
- Applicant: Evonik Degussa GmbH
- Applicant Address: DE Essen
- Assignee: Evonik Degussa GmbH
- Current Assignee: Evonik Degussa GmbH
- Current Assignee Address: DE Essen
- Agency: Law Office of: Michael A. Sanzo, LLC
- Priority: EP15155413 20150217
- International Application: PCT/EP2016/052273 WO 20160203
- International Announcement: WO2016/131652 WO 20160825
- Main IPC: C07D301/12
- IPC: C07D301/12 ; C07D303/02 ; B01D61/02 ; B01J23/34 ; C07C11/04 ; C07C11/06 ; C07C21/067

Abstract:
In the method for the epoxidation of an olefin, the olefin is continuously reacted with hydrogen peroxide in a mixed reactor in the presence of a water soluble epoxidation catalyst, comprising a manganese complex, the reaction is carried out in a reaction mixture comprising an aqueous liquid phase and an organic liquid phase with mixing of the liquid phases, reaction mixture is continuously withdrawn from the mixed reactor and separated into a separated aqueous phase and a separated organic phase, and part of the separated aqueous phase is continuously recycled into the mixed reactor, with the combined hold-up time of aqueous phase in withdrawing, separating phases and recycling aqueous phase being kept at less than 15 minutes.
Public/Granted literature
- US20180030012A1 METHOD FOR THE EPOXIDATION OF AN OLEFIN WITH HYDROGEN PEROXIDE Public/Granted day:2018-02-01
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