Invention Grant
- Patent Title: Oligomerization of ethylene to liquid transportation fuels with post synthesis treated ZSM-5 catalyst
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Application No.: US15216330Application Date: 2016-07-21
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Publication No.: US10207962B2Publication Date: 2019-02-19
- Inventor: Jianhua Yao , Bruce B. Randolph
- Applicant: PHILLIPS 66 COMPANY
- Applicant Address: US TX Houston
- Assignee: Phillips 66 Company
- Current Assignee: Phillips 66 Company
- Current Assignee Address: US TX Houston
- Agency: Phillips 66 Company
- Main IPC: C07C2/12
- IPC: C07C2/12 ; B01J29/40 ; C01B39/38 ; C01B39/02

Abstract:
A process for post synthesis treatment of ZSM-5 catalyst for converting ethylene to liquid fuel products providing substantially improved catalyst life. The treatment comprises either a base treatment, an acid treatment or a two-step treatment where one is with an acid and the other is with a base. The base treatment is provided by a weak sodium hydroxide such as less than 1 Molar concentration. The acid treatment is stronger acid where, for example, a hydrogen chloride solution at greater than 2 Molar concentration is used.
Public/Granted literature
- US20180022664A1 OLIGOMERIZATION OF ETHYLENE TO LIQUID TRANSPORTATION FUELS WITH POST SYNTHESIS TREATED ZSM-5 CATALYST Public/Granted day:2018-01-25
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