- Patent Title: Polymer, making method, resist composition, and patterning process
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Application No.: US13768545Application Date: 2013-02-15
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Publication No.: US10234757B2Publication Date: 2019-03-19
- Inventor: Masaki Ohashi , Tomohiro Kobayashi
- Applicant: SHIN-ETSU CHEMICAL CO., LTD.
- Applicant Address: JP Tokyo
- Assignee: SHIN-ETSU CHEMICAL CO., LTD.
- Current Assignee: SHIN-ETSU CHEMICAL CO., LTD.
- Current Assignee Address: JP Tokyo
- Agency: Westerman, Hattori, Daniels & Adrian, LLP
- Priority: JP2012-039622 20120227
- Main IPC: G03F7/004
- IPC: G03F7/004 ; C08F220/18 ; C08F220/38 ; C08F220/24 ; C08F220/28

Abstract:
A sulfonic acid anion-containing polymer having an alkylsulfonium cation not in covalent bond thereto can be readily prepared by reacting a sulfonic acid anion-containing polymer having an ammonium or metal cation with an alkylsulfonium salt under mild conditions. A resist composition comprising the inventive polymer is effective for suppressing acid diffusion since the sulfonium salt is bound to the polymer backbone. When processed by the ArF lithography, the polymer exhibits a lower absorption at the exposure wavelength than the triarylsulfonium salt form PAGs, resulting in improved resolution, mask fidelity, and LWR.
Public/Granted literature
- US20130224659A1 POLYMER, MAKING METHOD, RESIST COMPOSITION, AND PATTERNING PROCESS Public/Granted day:2013-08-29
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