Invention Grant
- Patent Title: Process for producing acetic acid
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Application No.: US15577524Application Date: 2017-11-17
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Publication No.: US10246399B2Publication Date: 2019-04-02
- Inventor: Masahiko Shimizu , Yoshihisa Mizutani , Hiroyuki Miura
- Applicant: Daicel Corporation
- Applicant Address: JP Osaka-Shi, Osaka
- Assignee: DAICEL CORPORATION
- Current Assignee: DAICEL CORPORATION
- Current Assignee Address: JP Osaka-Shi, Osaka
- Agency: Birch, Stewart, Kolasch & Birch, LLP
- Priority: JP2017-020775 20170207; JP2017-105771 20170529
- International Application: PCT/JP2017/041447 WO 20171117
- International Announcement: WO2018/146895 WO 20180816
- Main IPC: C07C51/12
- IPC: C07C51/12 ; C07C51/44 ; B01D3/00 ; B01D15/00 ; B01D15/36 ; B01J27/08 ; B01D3/14 ; B01J31/02

Abstract:
A process for producing acetic acid comprises a process comprising: (1) carbonylating methanol; (2) separating the reaction mixture into a volatile phase and a less-volatile phase; (3) distilling the volatile phase to form a first overhead rich in a lower boiling component, and an acetic acid stream rich in acetic acid; and at least one step group selected from the group consisting of the following sections (4), (9), and (15): (4) a section for separating impurities from the acetic acid stream to give purified acetic acid, (9) a section for separating the first overhead into a stream rich in acetaldehyde and a stream rich in methyl iodide, and (15) a section for absorption-treating an off-gas from the process with an absorption solvent and forming a carbon monoxide-rich stream and an acetic acid-rich stream. In this process, the concentration of oxygen in a gaseous phase of the process is controlled to less than 7% by volume and/or the concentration of oxygen in a liquid phase of the process is controlled to less than 7×10−5 g/g, and the formation of iodine is reduced. The process effectively reduces or prevents local corrosion of an inner wall of a process unit and/or line.
Public/Granted literature
- US20180354884A1 PROCESS FOR PRODUCING ACETIC ACID Public/Granted day:2018-12-13
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