Invention Grant
- Patent Title: Method of magnetic analysis to determine the catalytic activity of metal oxides including nanoceria
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Application No.: US15646863Application Date: 2017-07-11
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Publication No.: US10254249B2Publication Date: 2019-04-09
- Inventor: Vinod K. Paidi , Johan A. Van Lierop , Charles A. Roberts
- Applicant: The University of Manitoba , Toyota Motor Engineering & Manufacturing North America, Inc.
- Applicant Address: CA Winnipeg US KY Erlanger
- Assignee: The University of Manitoba,Toyota Motor Engineering & Manufacturing North America, Inc.
- Current Assignee: The University of Manitoba,Toyota Motor Engineering & Manufacturing North America, Inc.
- Current Assignee Address: CA Winnipeg US KY Erlanger
- Agency: Oblon, McClelland, Maier & Neustadt, L.L.P.
- Main IPC: B01J23/10
- IPC: B01J23/10 ; G01N27/72 ; G01R33/16

Abstract:
A method to predict the catalytic activity of a metal oxide of formula MxOy where x is a number from 1 to 3 and y is a number from 1 to 8 is provided. The metal of the metal oxide has redox coupled oxidation states wherein the redox transformation is between oxidation states selected from the group consisting of a diamagnetic oxidation state (Md+) and a paramagnetic oxidation state (Mp+), a paramagnetic oxidation state (Mp+) and a ferromagnetic oxidation state (Mf+), and a paramagnetic oxidation state (Mp+) and an antiferromagnetic oxidation state (Ma+)where d, p, f and a are independently numbers from 1 to 6 and one of the oxidation states (Md+), (Mp+), (Mf+), and (Ma+) is formed by reduction by the O2−. The magnetic susceptibility of the metal oxide as a sample in an oxygen environment at a specified temperature is correlated with a value of (Md+ or Mp+ or Mf+ or Ma+)/g (O2 rich). Then the magnetic susceptibility of the metal oxide as a sample in an oxygen free environment at the specified temperature is measured and correlated with a value of number of (Md+ or Mp+ or Mf+ or Ma+)/g (O2 deficient). The catalytic activity is predicted based on the difference of these two numbers.
Public/Granted literature
- US20190017964A1 METHOD OF MAGNETIC ANALYSIS TO DETERMINE THE CATALYTIC ACTIVITY OF METAL OXIDES INCLUDING NANOCERIA Public/Granted day:2019-01-17
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