Invention Grant
- Patent Title: Method for producing diesters of terephthalic acid with enrichment of recirculated alcohol
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Application No.: US15513775Application Date: 2015-09-21
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Publication No.: US10266477B2Publication Date: 2019-04-23
- Inventor: Armin Schraut , Martin Kaller , Rob Bronneberg , Jasmin Stammer , Martin Das , Gerrit Harnischmacher
- Applicant: BASF SE
- Applicant Address: DE
- Assignee: BASF SE
- Current Assignee: BASF SE
- Current Assignee Address: DE
- Agency: Drinker Biddle & Reath LLP
- Priority: EP14186137 20140924; EP15153483 20150202
- International Application: PCT/EP2015/071578 WO 20150921
- International Announcement: WO2016/046120 WO 20160331
- Main IPC: C07C67/08
- IPC: C07C67/08 ; B01D3/36 ; B01J19/00 ; C07C67/58

Abstract:
The present invention relates to a process for preparing a terephthalic diester by reacting terephthalic acid with at least one alcohol, wherein terephthalic acid is suspended in the alcohol in a dispersing tank, the preliminary suspension is passed from the dispersing tank into a reactor and converted in the presence of an esterification catalyst, and water of reaction is distilled off together with the vapor as alcohol-water azeotrope, the vapor is at least partly condensed, the condensate is separated into an aqueous phase and an organic phase and the organic phase is conducted through a column in which the organic phase is run counter to at least a portion of the vapor, and the organic phase is collected in the lower region of the column and at least partly passed into the dispersing tank.
Public/Granted literature
- US20170297998A1 METHOD FOR PRODUCING DIESTERS OF TEREPHTHALIC ACID WITH ENRICHMENT OF RECIRCULATED ALCOHOL Public/Granted day:2017-10-19
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