Invention Grant
- Patent Title: Continuous process for making polybutylene terephthalate using purified terephthalic acid and 1,4-butane diol
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Application No.: US15542677Application Date: 2016-01-29
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Publication No.: US10344119B2Publication Date: 2019-07-09
- Inventor: Husnu Alp Alidedeoglu , Prashant Kumar , Brian Bougher , Cornelis Adrianus Maria van Gool , Sasi Sethumadhavan Kannamkumarath , Bing Zhou
- Applicant: SABIC Global Technologies B.V.
- Applicant Address: NL Bergen op Zoom
- Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
- Current Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
- Current Assignee Address: NL Bergen op Zoom
- Agency: Cantor Colburn LLP
- International Application: PCT/EP2016/051886 WO 20160129
- International Announcement: WO2016/120429 WO 20160804
- Main IPC: C08G63/183
- IPC: C08G63/183 ; C08G63/78 ; B01J19/00

Abstract:
Disclosed is a continuous process and device for making polybutylene terephthalate (PBT) resin, particularly high molecular weight PBT resin. The process includes combining 1,4-butane diol and purified terephthalic acid to form a mixture and continuously supplying the mixture to a tower reactor having a plurality of reactor zones for esterification and/or transesterification. The product is continuously supplied to a first continuously stirred tank reactor, and further to a continuous polycondensation reactor. Particular conditions for each step of the process are further described herein. Also disclosed are a device for conducting the process, and a monitoring process for determining the carboxylic acid end group concentration of the resulting PBT.
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