In the present invention, in laminated separator rolls 12U and 12L, laminated long separator sheets 12a and 12b are wound such that a surface B (which is of an aramid layer (heat-resistant layer) and is opposite to a surface contacting with the porous film) faces an inner side (core u, l side). From this, it is possible to provide the laminated separator roll which can inhibit change in color of the porous layer included in the porous long separator sheet.