Invention Grant
- Patent Title: Free-radical polymerization methods and articles thereby
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Application No.: US15318296Application Date: 2015-06-29
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Publication No.: US10351642B2Publication Date: 2019-07-16
- Inventor: Zachary J. Thompson
- Applicant: 3M INNOVATIVE PROPERTIES COMPANY
- Applicant Address: US MN St. Paul
- Assignee: 3M Innovative Properties Company
- Current Assignee: 3M Innovative Properties Company
- Current Assignee Address: US MN St. Paul
- Agent Bradford B. Wright
- International Application: PCT/US2015/038291 WO 20150629
- International Announcement: WO2016/014218 WO 20160128
- Main IPC: C08F20/28
- IPC: C08F20/28 ; C08F4/06 ; C08F4/12 ; C08F4/26 ; C08F220/28 ; B32B7/12 ; B32B17/06

Abstract:
A method of curing a free-radically polymerizable composition includes contacting a curable composition with at least one metal oxide selected from the group consisting of magnesium oxide, ferrous metal oxides, aluminum oxide, nickel oxide, silver oxide, and combinations thereof. The curable composition includes: free-radically polymerizable compound; and a beta-dicarbonyl compound represented by the formula (I) or a salt thereof, wherein: X1 and X2 independently represent a covalent bond, wherein each R4 independently represents H or alkyl having from 1 to 18 carbon atoms; R1 and R2 independently represent a hydrocarbyl or substituted-hydrocarbyl group having from 1 to 18 carbon atoms, and R3 represents hydrogen, or a hydrocarbyl or substituted-hydrocarbyl group having from 1 to 18 carbon atoms, or taken together any two of R1, R2, or R3 form a five-membered or six-membered ring; an organic peroxide; and a quaternary ammonium halide. Articles including the cured compositions are also disclosed.
Public/Granted literature
- US20170137546A1 FREE-RADICAL POLYMERIZATION METHODS AND ARTICLES THEREBY Public/Granted day:2017-05-18
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