Invention Grant
- Patent Title: Compositions comprising cleavable crosslinker and methods
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Application No.: US15638469Application Date: 2017-06-30
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Publication No.: US10351649B2Publication Date: 2019-07-16
- Inventor: Jason D. Clapper , Dennis E. Vogel , Ann R. H. Fornof , Babu N. Gaddam
- Applicant: 3M INNOVATIVE PROPERTIES COMPANY
- Applicant Address: US MN St. Paul
- Assignee: 3M Innovative Properties Company
- Current Assignee: 3M Innovative Properties Company
- Current Assignee Address: US MN St. Paul
- Agent Carolyn A. Fischer
- Main IPC: C08F220/18
- IPC: C08F220/18 ; C08F220/26 ; C08F220/28 ; C09J133/04 ; C09J4/00 ; C08J3/28 ; C09J5/00 ; C09J5/06 ; C09J133/08 ; C09J7/38 ; C09J133/06 ; C09J133/10 ; C08F222/10

Abstract:
A composition is described comprising a polymer. The polymer comprises polymerized units derived from a cleavable crosslinking monomer. The cleavable crosslinking monomer comprises at least two free-radically polymerizable groups and at least one group having the formula —O—C(R2)(R3)—O—, wherein R2 and R3 are independently hydrogen, alkyl, or aryl. The composition has a Tg no greater than 50° C. In some embodiments, the composition has a storage modulus greater than 3×105 Pa at 25° C. and 1 Hz and may be characterized as a non-tacky polymer. In other embodiments, the composition is a pressure sensitive adhesive. Upon cleavage of at least a portion of the polymerized monomeric units derived from the cleavable crosslinking monomer, the composition exhibits a change in at least one physical property. In another embodiment, the composition comprises a polymer and fragments. The fragments comprise the reaction product of a free-radically polymerizable group bonded to a polymer chain and a pendent hydroxyl group. The composition has a Tg no greater than 50° C. Also described are articles, comprising the composition described herein (i.e. before and/or after cleavage); as well as methods of making the composition and methods of making articles.
Public/Granted literature
- US20170298163A1 COMPOSITIONS COMPRISING CLEAVABLE CROSSLINKER AND METHODS Public/Granted day:2017-10-19
Information query
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