Invention Grant
- Patent Title: Process for producing propylene copolymers in gas phase
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Application No.: US15510030Application Date: 2015-09-11
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Publication No.: US10364307B2Publication Date: 2019-07-30
- Inventor: Luigi Resconi , Norbert Hafner , Wilfried Töltsch
- Applicant: BOREALIS AG
- Applicant Address: AT Vienna
- Assignee: Borealis AG
- Current Assignee: Borealis AG
- Current Assignee Address: AT Vienna
- Agency: Gardner Groff Greenwald & Villanueva, PC
- Priority: EP14184641 20140912
- International Application: PCT/EP2015/070889 WO 20150911
- International Announcement: WO2016/038210 WO 20160317
- Main IPC: C08L23/16
- IPC: C08L23/16 ; C08L23/14 ; C08F210/06 ; C08F4/6592 ; C08F2/38 ; C08F4/659

Abstract:
A process for the preparation of a heterophasic copolymer of propylene and ethylene comprising polymerizing propylene and ethylene in the gas phase in the presence of a solid particulate catalyst free from an external carrier comprising: (i) a symmetrical complex of formula (I), wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from —R′2C—, —R′2C—CR′2-, —R′2Si—, —R′2Si—SiR′2—, —R′2Ge—, wherein each R′ is independently a hydrogen atom, C1-C20-alkyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; R2 is a C1-C20 hydrocarbyl radical; R5 is a C1-C20 hydrocarbyl radical; R6 is a tertiary C4-C20 hydrocarbyl radical; R7 is a hydrogen atom or a C1-10-hydrocarbyl radical; n is 0 to 3; R1 is a C1-C20 hydrocarbyl radical and optionally two adjacent R1 groups taken together can form a further mono or multicyclic ring condensed to Ph ring optionally substituted by one or two groups R4; and R4 is a C1-C10 alkyl radical and (ii) a cocatalyst, preferably comprising an organometallic compound of a Group 13 metal; wherein the xylene soluble fraction (XS) of the heterophasic copolymer of propylene and ethylene has an intrinsic viscosity of at least 1.5 dl/g and an ethylene content of 10 to 70 wt %.
Public/Granted literature
- US20170247484A1 PROCESS FOR PRODUCING PROPYLENE COPOLYMERS IN GAS PHASE Public/Granted day:2017-08-31
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