Invention Grant
- Patent Title: Batch process for making polybutylene terephthalate
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Application No.: US15320888Application Date: 2015-08-13
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Publication No.: US10364321B2Publication Date: 2019-07-30
- Inventor: Husnu Alp Alidedeoglu , Prashant Kumar
- Applicant: SABIC GLOBAL TECHNOLOGIES B.V.
- Applicant Address: NL Bergen op Zoom
- Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
- Current Assignee: SABIC GLOBAL TECHNOLOGIES B.V.
- Current Assignee Address: NL Bergen op Zoom
- Agency: Cantor Colburn LLP
- International Application: PCT/US2015/045004 WO 20150813
- International Announcement: WO2016/025684 WO 20160218
- Main IPC: C08G63/85
- IPC: C08G63/85 ; C08G63/183

Abstract:
A batch process for preparing polybutylene terephthalate (PBT) includes heating a solid PBT oligomer having an intrinsic viscosity (IV) of 0.1 to 0.2 dL/g and a carboxylic acid end group concentration [CEG] of 90 to 180 mmol/kg at a temperature and pressure defined herein to form melted homogeneous PBT oligomer containing 0 to 300 ppm tetra(C1-C8 alkyl) titanate catalyst, and polycondensing the melted homogeneous PBT oligomer in the presence of a tetra(C1-C8 alkyl) titanate catalyst, reducing the pressure, and maintaining the temperature at approximately 245-260° C. for a sufficient time to provide PBT having an IV of 0.55 and 1.20 dL/g. The PBT oligomer can be prepared by heating a mixture of 1,4-butane diol and purified terephthalic acid in the presence of a tetra(C1-C8 alkyl) titanate catalyst.
Public/Granted literature
- US20170198090A1 BATCH PROCESS FOR MAKING POLYBUTYLENE TEREPHTHALATE Public/Granted day:2017-07-13
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