This application provides a pixel structure of display array substrate and a display device applied thereto. The pixel structure of display array substrate includes a plurality of pixel units arranged in an array manner. Each pixel unit includes a first subpixel, a second subpixel, and a fourth subpixel. Each pixel unit further includes: a first subpixel electrode and a second subpixel electrode, respectively located in the first subpixel and the second subpixel; and a fourth subpixel electrode, where the fourth subpixel electrode includes a first pixel electrode, a second pixel electrode, a third pixel electrode, and a fourth pixel electrode located in four areas of the fourth subpixel, respectively, and each the first pixel electrode, the second pixel electrode, the third pixel electrode, and the fourth pixel electrode are divided into at least two compensation area.