Invention Grant
- Patent Title: Methods for the production of potassium sulphate from potassium-containing ores at high ambient temperatures
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Application No.: US15569207Application Date: 2016-05-04
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Publication No.: US10399861B2Publication Date: 2019-09-03
- Inventor: Richard W. Chastain , Ingrid T. Buckhurst , Antoine Lefaivre , Thomas H. Neuman
- Applicant: Yara Dallol BV
- Applicant Address: NL Sluiskil
- Assignee: YARA DALLOL BV
- Current Assignee: YARA DALLOL BV
- Current Assignee Address: NL Sluiskil
- Agency: Wenderoth, Lind & Ponack, L.L.P.
- Priority: NO20150571 20150508
- International Application: PCT/EP2016/059952 WO 20160504
- International Announcement: WO2016/180692 WO 20161117
- Main IPC: C01D5/00
- IPC: C01D5/00 ; C01D5/10 ; C01D5/16 ; C01F5/40

Abstract:
A method for the production of potassium sulphate comprising contacting an aqueous potassium- and sulphate-containing composition with magnesium chloride (MgCl2), thereby obtaining a composition comprising kainite; optionally concentrating the kainite from the composition; reacting the kainite with magnesium sulphate (MgSO4) and potassium sulphate (K2SO4) so as to convert the kainite into leonite (K2SO4.MgSO4.4H2O); optionally contacting the leonite with water to remove excess MgSO4; and contacting the leonite with water so as to leach the MgSO4, contained in the leonite, and to at least substantially selectively precipitate potassium sulphate (K2SO4). The method can be operated at higher temperatures, in particular, at temperatures above 35° C., and does not require a cooling step at 20 to 25° C. The method produces potassium sulphate with a low amount of chloride.
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