Provided is a microporous polyolefin membrane which has excellent oxidation resistance and electrolyte injection performance and further has excellent permeability and strength balance. The multilayer, microporous polyolefin membrane has a first microporous layer containing polypropylene. The electrolyte injection performance is 20 seconds or less, at least one surface layer is the first microporous layer, and the PP distribution in the first microporous layer is uniform in the in-plane direction.