Invention Grant
- Patent Title: Method for preparing aromatic hydrocarbon with carbon dioxide hydrogenation
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Application No.: US16085397Application Date: 2017-07-25
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Publication No.: US10464859B2Publication Date: 2019-11-05
- Inventor: Qingjie Ge , Jian Wei , Hengyong Xu
- Applicant: DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES
- Applicant Address: CN Dalian
- Assignee: DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES
- Current Assignee: DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES
- Current Assignee Address: CN Dalian
- Agency: VLP Law Group LLP
- Agent Enshan Hong
- Priority: CN201610832357 20160919
- International Application: PCT/CN2017/094192 WO 20170725
- International Announcement: WO2018/049919 WO 20180322
- Main IPC: C10G2/00
- IPC: C10G2/00 ; C07C1/12 ; B01J29/46 ; C07C15/06 ; C07C15/073 ; B01J29/40 ; B01J29/70 ; B01J29/76 ; B01J37/04 ; B01J37/06 ; B01J23/745 ; B01J37/00

Abstract:
A method for preparing aromatic hydrocarbons with carbon dioxide hydrogenation, comprising: directly converting a mixed gas consisting of carbon dioxide and hydrogen with the catalysis of a composite catalyst under reaction conditions of a temperature of 250-450° C., a pressure of 0.01-10.0 MPa, a feedstock gas hourly space velocity of 500-50000 mL/(h·gcat) and a H2/CO2 molar ratio of 0.5-8.0, to produce aromatic hydrocarbons. The composite catalyst is a mixture of a first component and a second component. The first component is an iron-based catalyst for making low-carbon olefin via carbon dioxide hydrogenation, and the second component is at least one of metal modified or non-modified molecular sieves which are mainly used for olefin aromatization. In the method, CO2 conversion per pass may be above 33%, the hydrocarbon product selectivity may be controlled to be above 80%, the methane content is lower than 8%, C5+ hydrocarbon content is higher than 65% and the proportion of the aromatic hydrocarbons in C5+ hydrocarbons may be above 63%.
Public/Granted literature
- US20190071374A1 METHOD FOR PREPARING AROMATIC HYDROCARBON WITH CARBON DIOXIDE HYDROGENATION Public/Granted day:2019-03-07
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