Oxidative dehydrogenation is an alternative to the energy extensive steam cracking process presently used for the production of olefins from paraffins, but has not been implemented commercially partially due to the unstable nature of hydrocarbon/oxygen mixtures, and partially due to the cost involved in the construction of new facilities. An oxidative dehydrogenation chemical complex designed to reduce costs by including integration of an oxygen separation module that also addresses safety concerns and reduces emission of greenhouse gases is described.