A plated steel sheet including an alloy plating layer formed on a surface of the steel sheet consisting of, in mass %, Cr: 5 to 91%, Fe: 0.5 to 10%, and the balance: Ni and unavoidable impurities, the Ni concentration gradually decreases from an outermost surface of the alloy plating layer to a side of the steel sheet, Ni/Cr>1 in an area extending 300 nm or more from the outermost surface of the alloy plating layer, the Fe concentration in the alloy plating layer gradually decreases from the side of the steel sheet to the outermost surface, the Fe concentration in the outermost surface 0.5% or less, the total thickness of an alloy layer formed in the alloy plating layer and containing Cr and Fe is 500 to 2000 nm, and the total amount of the alloy plating layer deposited to the steel sheet is 4.5 to 55.5 g/m2.