A radio-frequency (RF) transceiver front-end circuit includes an antenna, a power amplifier, a low-noise amplifier, a first switch unit and a second switch unit. The power amplifier is connected to a transmitting unit and the antenna to form a transmission path. The low-noise amplifier is connected to a receiving unit and the antenna to form a reception path. The transmission path and the reception path selectively do not include a λ/4 transmission line connected to the antenna. The RF transceiver front-end circuit has a receiving state and a transmitting state. In the receiving state, the first switch unit is controlled and causes the transmission path to have high impedance. In the transmitting state, the second switch unit is controlled and causes the reception path to have high impedance.