The present invention generally relates to nonwoven structures and composites comprising such nonwoven structures, particularly structures incorporating foam, and methods of making and use thereof. One aspect of the invention is generally directed to composites comprising a nonwoven structure immobilized to foam, e.g., using adhesive, needling, or other techniques. The nonwoven structure may comprise any of a variety of fibers. In certain embodiments, the composite may be substantially thermally insulating and/or acoustic insulating. Other aspects of the present invention are generally directed to systems and methods for making such composites, methods of use of such composites, kits comprising such composites, and the like.