Provided is a high-pressure fuel injection pipe with a connection head which achieves an improvement in outer-surface cleanliness and prevention of a decrease in axial force and fastening strength. The pipe having, at a connection end of a narrow-diameter thick-wall steel pipe having a rust-inhibiting coating applied to an outer surface of the pipe, the connection head composed of a spherically-shaped seat surface, an annular flange, and a conical surface and having an outside peripheral surface forming formed into seat surface in a truncated conical shape or truncated arc shape for a mating seat; and a washer fitting in a neck lower part of the connection head and having a rust-inhibiting coating applied to an outer surface of the washer, wherein a contact part between the neck lower part of the connection head and an end part of the washer has a metal-to-metal contact structure without having the rust-inhibiting coating.