An aluminum plastic film packaging material for lithium batteries to prolong service life, at least comprising an inner layer and an aluminum foil layer, is performed an anti-corrosion treatment between the inner layer and the aluminum foil layer by one of the following ways: 1) a chromium-containing anti-corrosion layer is formed from an aqueous modified resin containing trivalent chromium; and 2) an adhesive layer with non-chromium material is formed from an aqueous modified resin, an epoxy curing agent, a silane coupling agent and a nano-sized metal oxide particle.