• Patent Title: Method for manufacturing furan-2,5-dicarboxylic acid (FDCA) from a salt solution
  • Application No.: US15558244
    Application Date: 2016-03-17
  • Publication No.: US10577339B2
    Publication Date: 2020-03-03
  • Inventor: Jan Van KriekenAndre Banier De Haan
  • Applicant: PURAC BIOCHEM BV
  • Applicant Address: NL Gorinchem
  • Assignee: PURAC BIOCHEM BV
  • Current Assignee: PURAC BIOCHEM BV
  • Current Assignee Address: NL Gorinchem
  • Agency: Oliff PLC
  • Priority: EP15159401 20150317
  • International Application: PCT/EP2016/055820 WO 20160317
  • International Announcement: WO2016/146753 WO 20160922
  • Main IPC: C07D307/68
  • IPC: C07D307/68
Method for manufacturing furan-2,5-dicarboxylic acid (FDCA) from a salt solution
Abstract:
A method for manufacturing furan-2,5-dicarboxylic acid (FDCA) by converting a furan-2,5-dicarboxylate salt (MFDC) into FDCA, including the steps of combining an aqueous solution of MFDC with a concentration of at least 5 wt. % with an inorganic acid (HY), to form a reaction mixture including solid FDCA in a concentration of 1-15 wt. % in a salt solution resulting from the cation of furan-2,5-dicarboxylate salt and the anion of the inorganic acid (MY solution), removing solid FDCA from the reaction mixture in a solid/liquid separation step, and providing part of the MY solution resulting from the solid/liquid separation step to the step of combining MFDC with HY. The step of providing part of MY salt solution resulting from the solid/liquid separation step to the step of combining MFDC with HY makes it possible to obtain a stable and economic process which results in an FDCA product with good quality and high yield.
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