Disclosed is a composition including a network of cross-linked polymers. The network is prepared by one of the following radical copolymerisations. First, there is copolymerization of monomers, polymer of interest precursors, the monomers carrying at least one functional group that is polymerisable by radical polymerization. Second, there is copolymerization of monomers comprising at least one pending imine group and carrying at least one functional group that is polymerisable by radical polymerisation; and/or monomers comprising at least one pending aldehyde group and carrying at least one functional group that is polymerisable by radical polymerization. Third, there is a copolymerization of a cross-linking agent comprising aldehyde and/or imine groups enabling the formation of a cross-linked polymer network containing pending functions and cross-links that are exchangeable by aldehyde-imine exchange reactions and/or by imine-imine exchange reactions.