Example implementations relate to multicast multi-user grouping. For example, an apparatus may comprise a processing resource that may rank a plurality of stations associated with the apparatus based on a characteristic associated with a first multicast group containing a first set of stations among the plurality of stations, and a characteristic associated with a second multicast group containing a second set of stations among the plurality of stations. The processing resource may assign a first group of stations from the first multicast group and the second multicast group to a first multi-user group and assign a second group of stations from the first multicast group and the second multicast group to a second multi-user group. The processing resource may convert a multicast frame associated with a station from the first multi-user group to a unicast frame, and transmit the unicast frame to each station in the first multi-user group.