Invention Grant
- Patent Title: Method for the synthesis of metal nanoparticles in aqueous environment without the use of shape directing agents
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Application No.: US16062143Application Date: 2016-12-14
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Publication No.: US10596632B2Publication Date: 2020-03-24
- Inventor: Mauro Moglianetti , Pier Paolo Pompa
- Applicant: FONDAZIONE ISTITUTO ITALIANO DI TECNOLOGIA
- Applicant Address: IT Genoa
- Assignee: FONDAZIONE ISTITUTO ITALIANO DI TECNOLOGIA
- Current Assignee: FONDAZIONE ISTITUTO ITALIANO DI TECNOLOGIA
- Current Assignee Address: IT Genoa
- Agency: Silvia Salvadori, P.C.
- Agent Silvia Salvadori
- Priority: IT102015000083301 20151215
- International Application: PCT/IB2016/057607 WO 20161214
- International Announcement: WO2017/103807 WO 20170622
- Main IPC: B22F9/24
- IPC: B22F9/24 ; C30B7/14 ; C30B29/02 ; C30B29/60 ; B22F1/00 ; C30B29/66 ; B82Y40/00

Abstract:
The present disclosure relates to a seed-growth based method for the synthesis of metal nanoparticles of controlled shape (cubes, cuboids, octahedrons) and size in an aqueous environment, without the use of shape directing agents. The method involves a first step of preparing a solution comprising water, metal seed growth nanoparticles, a metal salt comprising the same metal as the metal seed growth nanoparticles, and a reducing agent; and a second step of heating the solution to between 9 and 130° C. at a rate of between 1° C./min and 5° C./min and at a pressure of between 1 and 5 atm. The method may also be carried out in a reduced oxygen atmosphere and the concentration of oxygen disclosed in the solution may be less than the concentration of oxygen in an oxygen saturated solution.
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