Low-water content organic phases can be difficult to achieve at high fluxes when water is present in an emulsified form, such as in a water-in-oil emulsion. Processes for de-emulsifying a fluid stream containing emulsified water, such as water-in-crude oil emulsions, include introduction of the fluid stream into a vessel that defines a coalescence zone. The vessel is configured to provide for simultaneous application of a centrifugal force and an electric field to the fluid stream within the coalescence zone. The simultaneous application of the centrifugal force and the electric field to the fluid stream provides for the coalescence of a portion of the emulsified water into a bulk aqueous phase. Continuous phases of the organic component and the bulk aqueous phase form in the coalescence zone and are separately removed from the vessel. The bulk aqueous phase is removed from the underside of the vessel.