There is disclosed a layered article that can be used in indirect printing, in analog or digital processes. The layered article, when configured as a transfer member, may serve to receive an ink in any form, allow the ink to be treated so as to form an ink image, and permit the application of the ink image on a substrate. The transfer member comprises a support layer and an imaging layer, which may be formed of a silicon matrix including dispersed carbon black particles. Methods for preparing the same are also disclosed.