A method for tracking and identifying a polluted air mass's transmission trajectory in real 3-D space. In one aspect, a polluted air mass's transmission path identification is based on a monitoring of PM2.5 concentration in cubic volumes of an air mass. The method computes a transmission path of polluted air that considers wind-pressure conversion, the displacement estimation with mass concentration, and planetary boundary layer (PBLP height constraint) for 3-D cubic grids. The resultant determination of a polluted air mass's transmission trajectory in real 3-D space generates more practical and reliable results for intensive knowledge of the transport pathways and potential pollution sources in real 3-D space.