A novel method of applying topical erectile dysfunction medicaments for controlled dispensing thereof through a condom or like prophylactic article is provided. Additionally, encompassed within this invention is the combination of an initial ingestion of a small dose of orally taken ED medicament for initial generation of nitric oxide followed by such a topical application. With such a method, the initial oral application metabolizes and runs its course while the topical application provides the needed dose of ED medicament. Once a sexual event is completed, the wearer may then remove the topical application article removing the topical delivery thereof in order to return to a flaccid state quickly and easily. Such an article and method thus reduces the propensity for potentially damaging excessive erection states and provides a more reliable dosing regimen for more effective and safe implementation of such an ED medicament program.