A method and system for de-oiling a feed comprising oil and water. The feed has an input temperature above the boiling point of water and an input pressure sufficient to maintain the water in a liquid state. In at least one embodiment, the method comprises pumping the feed with a motive pump through a phase separator having a restriction to effect a phase separation of oil and water in the feed and produce an agitated mixture, supplying the agitated mixture from the phase separator into a pressure vessel operating at a pressure sufficient to maintain in a liquid state water that is at a temperature above the boiling point of water, removing an oil phase from the pressure vessel, and removing a water phase from the pressure vessel.