The optical fiber offered is capable of not only restraining the attenuation due to glass defects, but also reducing the increase of manufacturing cost. The optical fiber is made of silica glass and includes a core and a cladding. The cladding encloses the core and has a refractive index smaller than that of the core. When the core is divided into inner core and outer core at half of the radius of the core, the average chlorine concentration of the inner core is larger than that of the outer core. The core includes any of the alkali metal group.